Donnayite occurs in pegmatite dykes, miarolitic cavities and interstices in nepheline syenite at Mont St-Hilaire,
Québec. Usually associated with microcline, analcime, calcite, natrolite, chlorite, aegirine, arfvedsonite and other minerals, donnayite, commonly occurs in syntactic intergrowths with ewaldite, a Sr analogue of ewaldite, mckelveyite, and rarely with synchysite. Crystals, 0.05 to 2mm, vary in habit from platy, tabular, columnar, saucer-shaped, barrel-shaped to irregularly granular; they are usually pale yellow to reddish brown, but also colorless, white, grey, brown to reddish brown, with a white streak and vitreous lustre. Hardness - 3. Dobs = 3.30 and Dcalc = 3.266 g/cm3. Basal cleavage indistinct to fair. Dissolves in HCl with strong effervescence. Optically, biaxial negative, with a 1.551-1.561, b 1.646, g 1.652, 2V 0-20º, X = c*. Donnayite is isomorphous with weloganite (as shown by the following unconventional setting): triclinic P1, a 9.000, b 8.999, c 6,793 Å, a 102.77, b 116.28, g 59.99º, Z = 1. The nine strongest powder diffraction lines are:
| 6.103 (4)(001) |
4.368 (7)(120, 211, 110) |
3.209 (3)(121, 111, 212) |
| 2.839 (10)(211, 112, 122) |
2.598 (4)(331, 030, 301) |
2.038 (3)(310, 113, 212, 003) |
| 2.018 (3)(242, 222, 420) |
1.978 (3)(333, 303, 032, 301, 331) |
1.694 (3)(542, 512, 140, 150, 411, 451, 214, 113) |
Twinning by rotation about
[103]120º and by reflection across (010, (301) or (331) is extremely common. Electron microprobe analysis gives:
| Na2O 3.37 |
CaO 5.75 |
BaO 0.85 |
SrO 35.8 |
Y2O3 13.1 |
| Nd2O3 1.83 |
La2O3 0.45 |
CO2 (30.98) |
H2O (6.34) |
|
sum 98.47%. CO2 and H2O are assumed to be stoichiometric. The analysis corresponds to Na0.93(Ca0.87Nd0.09La0.03)(Sr2.95Ba0.05)(Y0.99(CO3)6 · 3H2O, or ideally
NaCaSr3Y(CO3)6 · 3H2O. New data show that mckelveyite is also triclinic, isomorphous with weloganite and donnayite; its original analysis may be recalculated to (Na1.29K0.02)(Ca0.73U0.17)(Ba2.72Sr0.17)(Y0.70RE0.32)(CO3)6 · 3.48 H2O, close to NaCaBa3Y(CO3)6 · 3H2O. |